On my previous TD6 I could set each key to the user so if my wife disarmed the car with her key, the seat and mirrors would I adjust to her settings.
I’ve noticed our TDV8 doesn’t do this. Is there a way of enabling it? 2010 MY Vogue SE TDV8 3.6 Stornoway Grey- fully loaded

I believe there is, if you look in your handbook it will tell you in there. I'm sure it's something to do with the memory seats. Insert key 1 into ignition, adjust everything to your liking, seats, mirrors, steering wheel even the radio stations, then store to number one memory button on side of seat. Same again for key 2, just insert into ignition and then store to number 2 memory on side of seat. So then when either key is used to unlock car, everything should be adjusted to the corresponding key. Hope this helps

This is a 2010. No ignition barrel. 2010 MY Vogue SE TDV8 3.6 Stornoway Grey- fully loaded

Ah sorry. Still, have a look in your handbook I'm very sure it will tell you in there. It's what I had to do in mine (2008) and took about 4 attempts to get it to store.